Clostridium perfringens as a potential indicator for the presence of sewage solids in marine sediments     

Skanavis C  Yanko WA 《Marine pollution bulletin》2001,42(1):31-35

Marine sediment cores collected from several depths of water and distances from a California sewage outfall were tested to see if sediments influenced by sewage solids were a reservoir of enteric pathogens, and if concentrations of indicator bacteria were related to the presence of sewage solids. Vertical distributions of microorganisms in marine sediments were determined; there was a decrease of indicator bacteria with increasing sediment depth. Aeromonas was randomly isolated, but none of the enteric bacterial pathogens or viruses were detected. While classic indicator bacteria were of little value in predicting the presence of pathogens, or relative amounts of sewage solids, Clostridium perfringens may be a suitable indicator. Clostridium perfringens concentrations were not related to the presence of pathogens in sediments.  相似文献   

Holistic environmental assessment and offshore oil field exploration and production     

Salter E  Ford J 《Marine pollution bulletin》2001,42(1):45-58

According to UK Government surveys, concern for the environment is growing. Environmental regulation of the industry is becoming wider in its scope and tougher in its implementation. Various techniques are available to assess how the industry can drive down its environmental impact and comply with environmental regulation. Environmental Assessments (EA) required by European law do not cover the whole life cycle of the project that they are analysing. Life Cycle Analysis (LCA) was developed to assess the environmental loadings of a product, process or activity over its entire life cycle. It was the first technique used in environmental analysis that adopted what was described as a holistic approach. It fails this approach by not assessing accidental emissions or environmental impacts other than those that are direct. Cost Benefit Analysis (CBA) offers the opportunity to value environmental effects and appraise a project on the basis of costs and benefits. Not all environmental effects can be valued and of those that can there is considerable uncertainty in their valuation and occurrence. CBA cannot satisfactorily measure the total environmental risk of a project. Consequently there is a need for a technique that overcomes the failures of project-level EA, LCA and CBA, and assesses total environmental risk. Many organizations such as, the British Medical Association, the European Oilfield Speciality Chemicals Association, the Royal Ministry of Petroleum and Energy (Norway) and Shell Expro now recognize that a holistic approach is an integral part of assessing total risk. The Brent SPAR case study highlights the interdisciplinary nature required of any environmental analysis. Holistic Environmental Assessment is recommended as such an environmental analysis.  相似文献   

Sources of salinity in ground water from Jericho area, Jordan Valley     

Marie A  Vengosh A 《Ground water》2001,39(2):240-248

One of the major problems in the lower Jordan Valley is the increasing salinization (i.e., chloride content) of local ground water. The high levels of salinity limit the utilization of ground water for both domestic and agriculture applications. This joint collaborative study evaluates the sources and mechanisms for salinization in the Jericho area. We employ diagnostic geochemical fingerprinting methods to trace the potential sources of the salinity in (1) the deep confined subaquifer system (K2) of Lower Cenomanian age; (2) the upper subaquifer system (K1) of Upper Cenomanian and Turonian ages; and (3) the shallow aquifer system (Q) of Plio-Pleistocene ages. The chemical composition of the saline ground water from the two Cenomanian subaquifers (K1 and K2) point to a single saline source with Na/Cl approximately 0.5 and Br/Cl approximately 7 x 10(-3). This composition is similar to that of thermal hypersaline spring that are found along the western shore of the Dead Sea (e.g., En Gedi thermal spring). We suggest that the increasing salinity in both K1 and K2 subaquifers is derived from mixing with deep-seated brines that flow through the Rift fault system. The salinization rate depends on the discharge volume of the fresh meteoric water in the Cenomanian Aquifer. In contrast, the chemical composition of ground water from the Plio-Pleistocene Aquifer shows a wide range of Cl- (100-2000 mg/L), Na/Cl (0.4-1.0), Br/Cl (2-6 x 10(-3)), and SO4/Cl (0.01-0.4) ratios. These variations, together with the high SO4(2-), K+, and NO3- concentrations, suggest that the salinity in the shallow aquifer is derived from the combination of (1) upconing of deep brines as reflected by low Na/Cl and high Br/Cl ratios; (2) leaching of salts from the Lisan Formation within the Plio-Pleistocene Aquifer, as suggested by the high SO4(2-) concentrations; and (3) anthropogenic contamination of agriculture return flow and sewage effluents with distinctive high K+ (80 mg/L) and NO3- (80 mg/l) contents and low Br/Cl ratios (2 x 10(-3)). Our data demonstrates that the chemical composition of salinized ground water can be used to delineate the sources of salinity and hence to establish the conceptual model for explaining salinization processes.  相似文献   

A comparison of solute-transport solution techniques and their effect on sensitivity analysis and inverse modeling results   总被引：1，自引：0，他引：1  

Mehl S  Hill MC 《Ground water》2001,39(2):300-307

Five common numerical techniques for solving the advection-dispersion equation (finite difference, predictor corrector, total variation diminishing, method of characteristics, and modified method of characteristics) were tested using simulations of a controlled conservative tracer-test experiment through a heterogeneous, two-dimensional sand tank. The experimental facility was constructed using discrete, randomly distributed, homogeneous blocks of five sand types. This experimental model provides an opportunity to compare the solution techniques: the heterogeneous hydraulic-conductivity distribution of known structure can be accurately represented by a numerical model, and detailed measurements can be compared with simulated concentrations and total flow through the tank. The present work uses this opportunity to investigate how three common types of results--simulated breakthrough curves, sensitivity analysis, and calibrated parameter values--change in this heterogeneous situation given the different methods of simulating solute transport. The breakthrough curves show that simulated peak concentrations, even at very fine grid spacings, varied between the techniques because of different amounts of numerical dispersion. Sensitivity-analysis results revealed: (1) a high correlation between hydraulic conductivity and porosity given the concentration and flow observations used, so that both could not be estimated; and (2) that the breakthrough curve data did not provide enough information to estimate individual values of dispersivity for the five sands. This study demonstrates that the choice of assigned dispersivity and the amount of numerical dispersion present in the solution technique influence estimated hydraulic conductivity values to a surprising degree.  相似文献   

Quantitative measurement of channel-block hydraulic interactions by experimental saturation of a large, natural, fissured rock mass     

Guglielmi Y  Mudry J 《Ground water》2001,39(5):696-701

The hydrodynamic behavior of fissured media relies on the relationships between a few very conductive fractures (channels) and the remaining low-conductivity fractures and matrix (blocks). We made a quantitative measurement of those relationships and their effect on water drainage and storage in a 19,000 m3 natural reservoir consisting of karstified limestones. This reservoir was artificially saturated with water by closing a water gate on the main outlet during a varying time (delta t) fixed by the operator. The water gate was completely or partly closed until the water pressure reached a particular specified value. If the water gate was left completely closed long enough, the water pressure was fixed by the elevation of temporary outlets at the site boundaries. The water elevation within the reservoir was monitored by means of pressure cells located on single fractures representative of the bedding plane and the two families of fractures of the massif network. The comparison of pressure variations with the network geometry allows us to identify a typical double permeability characterized by a few very conductive channels along 10 vertical faults. These channels limit blocks consisting of low-conductivity bedding planes and a rather impervious matrix. Depending on the closure interval, delta t, of the water gate, the total volume of water stored in the reservoir can vary from 0.8 m3 (delta t = 5 minutes) to 18.6 m3 (delta t = 2 days). Such a variance of storage versus closure time is explained by the reservoir's double permeability that is characterized by blocks that saturate much more slowly than channels. If plotted versus time, this injected volume fits a power relationship, according to the saturation state of the blocks. In less than 34 minutes, storage is close to zero in the blocks and to 1.6 to 2 m3 in the channels. For closing times shorter than 1 hour, only 1% of the volume that flows in the channels is stored into the blocks. Depending on the water pressure and for a given delta t = 3000 minutes, the volume of water stored is controlled by the geometry of the joint network and of the aquifer boundaries. Such an experiment shows that the flow is concentrated in about 10% of the fractured network (channels). The water storage that takes place in the 90% remaining fractures (blocks) depends mainly on time during which pressure remains high into the 10% channels. The accurate modeling of such typical double-permeability media needs a careful study of the geometry of the channels whose narrowings modify the flow and induce dam effects that maintain a high pressure gradient with surrounding blocks.  相似文献   

Sorption of radioactive contaminants by sediment from the Kara Sea     

Fuhrmann M  Zhou H  Neiheisel J  Dyer R 《Marine pollution bulletin》2001,43(1-6):102-110

The purpose of this study is to quantify some of the parameters needed to perform near-field modelling of sites in the Kara Sea that were impacted by the disposal of radioactive waste. The parameters of interest are: the distribution coefficients (Kd) for several important radionuclides, the mineralogy of the sediment, and the relationship of Kd to liquid-to-solid ratio. Sediment from the Kara Sea (location: 73 degrees 00'N, 58 degrees 00'E) was sampled from a depth of 287 m on August 23/24, 1992. Analysis of the material included mineralogy, grain size and total organic carbon (TOC). Uptake kinetics were determined for 85Sr, 137Cs, 241Am, 99Tc, 1251, 232U and 210Pb and distribution coefficients (Kd) were determined for these radionuclides using batch type experiments. Sorption isotherms, developed for 137Cs, 85Sr and 99Tc, were linear in each case. Increasing the liquid-to-solid ratio strongly increased uptake of 137Cs and moderately increased uptake of 99Tc. Analysis for anthropogenic radionuclides indicated the presence only of 239/240Pu in the sediment with the highest activity (at the top section of the core) being 0.420 Bq kg(-1). Other anthropogenic radionuclides were below detection limits.  相似文献   

Northern ocean inventories of organochlorine and heavy metal contamination     

Crane K  Galasso J  Brown C  Cherkashov G  Ivanov G  Petrova V  Vanstayan B 《Marine pollution bulletin》2001,43(1-6):28-60

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The main issues affecting coasts of the Indian and western Pacific Oceans: a meta-analysis from Seas at the Millennium     

Sheppard C 《Marine pollution bulletin》2001,42(12):1199-1207

A review of the world oceans in three volumes by 365 scientists, provides scope for several ‘meta-analyses' of the main problems affecting over 100 areas in the year 2000. This article summarises the main issues affecting a sub-set of the reviewed areas, covering Asian, African and Arabian countries dealt with in Volume 2, which included over 50 articles. From all issues raised, assessment is made of the nature of the major ones, including evaluation of reasons why so many of them remain important issues after so much attention to them. These include long standing problems, several problems more newly flagged as becoming particularly important, the issue of global warming and no less than three related issues connected with fishing and over exploitation. One or two issues such as industrial pollution and sewage, previously considered of almost universal concern, almost traditional pollution issues even, continue to feature strongly for some countries, but while these were almost always referred to in Seas chapters, by and large these categories appear not to be the most pressing of issues today, except in localized areas (albeit areas where huge numbers of people live). Perhaps other issues have simply taken over. They are excluded from this article.  相似文献   

Hydrocarbons in surface sediments from the Changjiang (Yangtze River) Estuary, East China Sea   总被引：9，自引：0，他引：9  

Bouloubassi I  Fillaux J  Saliot A 《Marine pollution bulletin》2001,42(12):1335-1346

Sedimentary aliphatic (AH) and polycyclic aromatic hydrocarbons (PAHs) were studied in the Changjiang Estuary and the adjacent East China Sea. Total AH ranged from 2.20 to 11.82 μg g⁻¹ and consisted of n-alkanes and a dominant petroleum-related unresolved complex mixture (UCM). Within the n-alkanes, terrestrial plant wax compounds prevailed at nearly all stations. Of the PAHs, biogenic perylene dominated at stations receiving riverine inputs. Anthropogenic PAHs originating from combustion/pyrolysis processes varied from 17 to 157 ng g⁻¹, while fossil PAH concentrations ranged from 42 to 187 ng g⁻¹. Both biogenic and anthropogenic hydrocarbons are primarily derived from riverine discharges and accumulate at shallow-water stations. Distinct phase associations lead, nevertheless, to different sedimentation patterns. Fossil PAHs are enhanced at offshore stations where they are introduced directly by shipping activities. Biomarker fingerprints ascribe their source to Chinese crude oils. The overall levels of anthropogenic hydrocarbons are low compared to relevant areas worldwide and reveal a low/moderate level of hydrocarbon pollution.  相似文献   

Lysosomal membrane stability and metallothioneins in digestive gland of Mussels (Mytilus galloprovincialis Lam.) as biomarkers in a field study     

Petrović S  Ozretić B  Krajnović-Ozretić M  Bobinac D 《Marine pollution bulletin》2001,42(12):1373-1378

The lysosomal membrane destabilization and the metallothionein content in the digestive gland cells of mussels (Mytilus galloprovincialis Lam.), collected along the east coast of the North Adriatic (Istrian and Kvarnerine coast, Croatia), were examined over a period of four years (1996–1999). The lysosomal membrane stability, as a biomarker of general stress, showed that the membrane labilization period in mussels from polluted, urban- and industrial-related areas was significantly decreased (p<0.05) when compared to mussels from control, clean sea water sites. In the harbour of Rijeka, the most contaminated site, the lysosomal membrane stability was reduced by more than 70% compared to the control. This method also proved to be a useful biomarker for detection of additional stress caused by short-term hypoxia that occurred once during this study inside the polluted and periodically quite eutrophic Pula Harbour. The concentration of metallothioneins in the mussel digestive gland, as a specific biomarker of exposure to heavy metals, did not reveal significant differences (p<0.05) between sites covered by this study.  相似文献